Control of cationic nanogel PEGylation in heterogeneous ARGET ATRP emulsion polymerization with PEG macromonomers
نویسندگان
چکیده
منابع مشابه
Use of a simple surface-active initiator in controlled/living free-radical miniemulsion polymerization under AGET and ARGET ATRP conditions.
This communication describes the first example of the efficient use of a simple amphiphilic molecule as both a surfactant and an initiator in the miniemulsion polymerization of methyl methacrylate under AGET and ARGET ATRP conditions.
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نانوکامپوزیت‌های پلی‌استیرن/MCM–41 به روش پلیمرشدن رادیکالی انتقال اتم (ATRP) در دمای 110 درجه سلسیوس سنتز شدند. روش‌های آغاز فعال‌کننده‌هایی که با انتقال الکترون تولید می‌شوند (AGET) و فعال‌کننده‌هایی که با انتقال الکترون بازتولید می‌شوند (ARGET) به عنوان دو روش نوین آغاز در ATRP به کار گرفته شدند. ساختار ویژه، مساحت سطح، اندازه ذرات و توزیع آنها و ساختار اسفنجی و حفره‌ای نانوذرات MCM–41 سنت...
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ژورنال
عنوان ژورنال: Journal of Polymer Science Part A: Polymer Chemistry
سال: 2018
ISSN: 0887-624X
DOI: 10.1002/pola.29035